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Ferrocenes were studied as cyclopentadiene ring surrogates enroute to non-metallocene targets such as the aminofulveno[1,2-b]chromone natural product chalaniline A. Ferroceno[b]chromone, as an archetype of interest, was prepared from ferrocenecarboxylic acid (4 steps, 24% yield) via N,N-diethyl 2-iodoferrocenecarboxamide by Ullmann etherification with phenol followed by LDA-mediated anionic cyclization. Reactivity studies revealed that this planar chiral analogue of xanthone readily fragments into non-metallocene products upon reaction with electrophiles. 1-Methoxy-3-methylferroceno[b]chromone, prepared similarly by substituting O-methylorcinol for phenol, was advanced to chalaniline A and a transposed regioisomer by concomitant deferration and demethylation with AlCl3; formylation of the resulting cyclopentadiene-fused chromone with excess Vilsmeier reagent; and then Pinnick oxidation (NaClO2), methylation (TMSCHN2), and final transamination (PhNH2). Four compounds, including ferroceno[b]chromone and the C11/C12-transposed regioisomer of chalaniline A, were characterized by single crystal X-ray diffraction analysis. 

The Nama Group (Kalahari Craton) is an archetypal stratigraphic record of the Ediacaran–Cambrian transition. The upper Schwarzrand Subgroup preserves key biostratigraphic markers of this interval, including erniettomorphs, cloudinomorphs, and trace fossils, yet has a complex stratigraphic architecture due to deposition in a foreland basin. Here, we describe the stratigraphy of the upper Schwarzrand Subgroup of the Nama Basin, and collate sedimentologic, geochronologic, carbon isotope chemostratigraphic, and biostratigraphic data. We argue that strata previously identified as the Nomtsas Formation in the Witputs Subbasin are lithostratigraphically and tectonostratigraphically distinct from those in the type area (Farm Nomtsas) in the Zaris Subbasin. Therefore, we introduce the Swartkloofberg Formation as a new name for the terminal Schwarzrand Subgroup in the Witputs Subbasin. While carbonates of the underlying Urusis Formation were deposited within shallow marine environments, the Swartkloofberg Formation records a transition to dominantly siliciclastic deposition, mostly below fair-weather wave base, and with extensive evidence of slope instability. High-relief stromatolite reefs formed diachronously at different localities within both the Urusis and Swartkloofberg formations due to laterally variable accommodation space within the foreland basin. Strata of the Swartkloofberg Formation are interpreted as flysch deposits within an underfilled basin. We propose that the distinct deltaic peritidal and shoreface strata that—in some localities—were previously assigned to the upper Nomtsas Formation, are placed within the unconformably overlying molasse deposits of the Fish River Subgroup. These strata contain the stratigraphically lowest identified occurrences ofTreptichnus pedumwithin the Nama Group, and thus the base of the Cambrian Period. This stratigraphic revision solves several longstanding issues with regional correlation and revises the position of the Ediacaran–Cambrian boundary in the Witputs Subbasin. Accordingly, the Swartkloofberg Formation in the Witputs Subbasin (538.5–<537.6 Ma) is Ediacaran in age, as defined by biostratigraphy, supporting recent interpretations that the base of the Cambrian Period may be younger than 537.6 Ma. With increasingly refined age-stratigraphic models for the Nama Group, the upper Schwarzrand Subgroup provides a high-resolution record of the evolution of increasingly complex benthic invertebrate behaviors in the terminal Ediacaran lead-up to the classical Cambrian radiation of biomineralized invertebrate phyla. 

Abstract. Permafrost degradation in Arctic lowlands is a critical geomorphic process, increasingly driven by climate warming and infrastructure development. This study applies an integrated geophysical and surveying approach – Electrical Resistivity Tomography (ERT), Ground Penetrating Radar (GPR), and thaw probing – to characterize near-surface permafrost variability across four land use types in Utqiaġvik, Alaska: gravel road, snow fence, residential building and undisturbed tundra. Results reveal pronounced heterogeneity in thaw depths (0.2 to >1 m) and ice content, shaped by both natural features such as ice wedges and frost heave and anthropogenic disturbances. Roads and snow fences altered surface drainage and snow accumulation, promoting differential thaw, deeper active layers, and localized ground deformation. Buildings in permafrost regions alter the local thermal regime through multiple interacting factors – for example, solar radiation, thermal leakage, snow cover dynamics, and surface disturbance – among others. ERT identified high-resistivity zones (>1,000 Ω·m) interpreted as ice-rich permafrost and low-resistivity features (<5 Ω·m) likely associated with cryopegs or thaw zones. GPR delineated subsurface stratigraphy and supported interpretation of ice-rich layers and permafrost features. These findings underscore the strong spatial coupling between surface infrastructure and subsurface thermal and hydrological regimes in ice-rich permafrost. Geophysical methods revealed subsurface features and thaw depth variations across different land use types in Utqiaġvik, highlighting how infrastructure alters permafrost conditions. These findings support localized assessment of ground stability in Arctic environments.